The sun is the major supplier of energy for the Earth's atmosphere and ocean. The sun's energy input (at the Earth's distance from the sun) is S=1376 W/m2. Roughly three quarters of this energy is reflected by clouds and ice, so the earth only takes in This energy is distributed over the illuminated part of the Earth, which has an area of pi R2. The total area of the earth is 4pi R2, so the average energy received on earth is 344 W/m2. A portion of this energy (alpha) is reflected by clouds and ice, so the earth receives (1-alpha)344 W/m2 = 241 W/m2.
The energy that comes into the Earth's atmosphere and ocean balances the
energy that the Earth sends into space. (If they didn't roughly balance,
the Earth would very rapidly heat up. ) Outgoing radiation is
longwave blackbody radiation and is equal to sigma T4.
The Boltzman constant, sigma = 5.7 x 10-8 W/(m2K4).
If sigma T4 = (1-alpha)S/4, we can predict the temperature of the
Earth to be: T=((1-alpha)/sigma S/4)1/4 = 255 K or about
-18C. The average temperature of the Earth is quite a bit warmer,
essentially because the Earth's atmosphere acts like a greenhouse, trapping
heat.
The Earth's atmosphere actually lets solar radiation pass through to reach
the Earth's surface, but it readily absorbs and reradiates outgoing longwave
radiation. We can represent this by creating a cloud layer that absorbs
some fraction of longwave radiation (epsilon) and reradiates this energy.
Then we write an energy balance for the lower atmosphere below the cloud and
one for the region above the cloud. Above the cloud: S/4 =
alpha S/4 + sigma Tc4 + (1-epsilon)sigma Te4.
Below the cloud: (1-alpha)S/4 + sigma Tc4 = sigma Te4.
This gives two equations and two unknowns. Solving for Te4,
we find that, if epsilon = 1, the temperature should be a factor of 21/4
warmer than in the previous example, or about 30C. In reality,
temperature on Earth is somewhere between -18 and 30C, but clearly we need an
absorbing layer in the atmosphere to explain why this planet is warm enough for
us to live here.
The major
greenhouse gases are all 3 atom molecules: H2O, CO2,
CH4, N2O, etc. With the exception of water vapor,
most greenhouse gas concentrations have increased substantially since the start
of industrialization. CO2, for example, has increase from
about 280 ppmv to 360 ppmv since 1850, and it has been monitored closely at
Mauna Loa since the mid 1950's by Dave Keeling of Scripps Institution of
Oceanography. CO2 increases are essentially entirely due to
the burning of fossil fuels. Methane and N2O have also
increased substantially.

Here's a summary of greenhouse gas increases and the effective increase in
radiative warming:
|
gas |
pre-1850 |
now |
radiative forcing |
|
CO2 |
280 ppmv |
360 ppmv |
1.56 Wm2 |
|
CH4 |
700ppbv |
1714 ppbv |
0.47 Wm2 |
|
N2O |
275 ppbv |
311 ppbv |
0.14 Wm2 |
Greenhouse gas concentrations continue to rise in the atmosphere, and the
overall impact of this increase is not fully understood, although an obvious guess
is that we'd predict the Earth to warm as greenhouse gas concentrations
increase.
In response to rising greenhouse gas concentrations and the overall uncertainties in the climate impact, in 1988 the Intergovernmental Panel on Climate Change was formed with a mandate to assess scientific data, assess socio-economic impacts of rising greenhouse gases, and formulate a response. That led to full reports in 1990 and 1995. The 2000 report is due out any day now. These are excellent resources for finding out about greenhouse warming.
In addition, in December 1997, the Kyoto Protocol was
negotiated. This is a formal agreement to reduce emissions
globally, while allowing nondeveloped countries to develop. It commits
countries to reduce greenhouse gas emissions to a fixed percentage of 1990
levels (92% for most of Europe and 93% for the US)---since most developed
countries have continued to build highways and cars and have expanded our
populations, the commitments in the Kyoto Protocol will be very challenging.
In the US, treaties are ratified by the Senate, and the Senate has not yet
attempted to discuss ratifying the Kyoto Protocol. See Kyoto Protocol text or commentaries
or search the web for more information.